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| 1,10-phenanthroline ： ウィキペディア英語版 |
Phenanthroline
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Phenanthroline (phen) is a heterocyclic organic compound. It is a white solid that is soluble in organic solvents. It is used as a ligand in coordination chemistry, it forms strong complexes with most metal ions.〔 In terms of its coordination properties, phen is similar to 2,2'-bipyridine (bipy).
==Synthesis==
Phenanthroline may be prepared by two successive Skraup reactions of glycerol with ''o''-phenylenediamine, catalyzed by sulfuric acid, and an oxidizing agent, traditionally aqueous arsenic acid or nitrobenzene. Dehydration of glycerol gives acrolein which condenses with the amine followed by a cyclization.
抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』
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