翻訳と辞書 ・ 1,3-Dioxane ・ 1,3-Dioxetane ・ 1,3-Dioxetanedione ・ 1,3-Dipolar cycloaddition ・ 1,3-dipole ・ 1,3-Dithietane ・ 1,3-Indandione ・ 1,3-Propane sultone ・ 1,3-Propanediol ・ 1,3-propanediol dehydrogenase ・ 1,3-Propanedithiol ・ 1,3-Thiazepine ・ 1,4,2-Dithiazole ・ 1,4,6-Androstatriene-3,17-dione ・ 1,4,7-Triazacyclononane ・ 1,4,7-Trithiacyclononane ・ 1,4-a-glucan 6-a-glucosyltransferase ・ 1,4-Benzodioxine ・ 1,4-Benzoquinone ・ 1,4-beta-D-xylan synthase ・ 1,4-Butanediol ・ 1,4-Butynediol ・ 1,4-Cycloheptadiene ・ 1,4-Cyclohexadiene ・ 1,4-Cyclohexanedione ・ 1,4-Diamino-2,3-dihydroanthraquinone ・ 1,4-Diazepine ・ 1,4-Dibromobenzene ・ 1,4-Dichloro-2-nitrobenzene ・ 1,4-Dichlorobenzene
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1,4,7-Trithiacyclononane : ウィキペディア英語版 | 1,4,7-Trithiacyclononane
|Section2= |Section7= |Section8= }} 1,4,7-Trithiacyclononane, also called 9-ane-S3, is the heterocyclic compound with the formula (CH2CH2S)3. This cyclic thioether is most often encountered as a tridentate ligand in coordination chemistry. 9-ane-S3 forms complexes with many metal ions, including those considered hard, such as copper(II) and iron(II). Most of its complexes have the formula ()2+ and are octahedral. The point group of ()2+ is S6. ==Synthesis== This compound was first reported in 1977, and the current synthesis entails the assembly within the coordination sphere of a metal ion followed by decomplexation: :500px
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