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・ 1,3-Indandione
・ 1,3-Propane sultone
・ 1,3-Propanediol
・ 1,3-propanediol dehydrogenase
・ 1,3-Propanedithiol
・ 1,3-Thiazepine
・ 1,4,2-Dithiazole
・ 1,4,6-Androstatriene-3,17-dione
・ 1,4,7-Triazacyclononane
・ 1,4,7-Trithiacyclononane
・ 1,4-a-glucan 6-a-glucosyltransferase
・ 1,4-Benzodioxine
・ 1,4-Benzoquinone
・ 1,4-beta-D-xylan synthase
・ 1,4-Butanediol
1,4-Butynediol
・ 1,4-Cycloheptadiene
・ 1,4-Cyclohexadiene
・ 1,4-Cyclohexanedione
・ 1,4-Diamino-2,3-dihydroanthraquinone
・ 1,4-Diazepine
・ 1,4-Dibromobenzene
・ 1,4-Dichloro-2-nitrobenzene
・ 1,4-Dichlorobenzene
・ 1,4-Dichlorobut-2-ene
・ 1,4-dihydroxy-2-naphthoate polyprenyltransferase
・ 1,4-dihydroxy-2-naphthoyl-CoA hydrolase
・ 1,4-Dihydroxyanthraquinone
・ 1,4-Dimethoxybenzene
・ 1,4-Dioxane


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1,4-Butynediol : ウィキペディア英語版
1,4-Butynediol

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1,4-Butynediol is an organic compound that is an alkyne and a diol. It is a colourless, hygroscopic solid that is soluble in water and polar organic solvents. It is a commercially significant compound in its own right and as a precursor to other products.
==Synthesis==
1,4-Butynediol can be produced in the Reppe synthesis, where formaldehyde and acetylene are the reactants:〔Heinz Gräfje, Wolfgang Körnig, Hans-Martin Weitz, Wolfgang Reiß, Guido Steffan, Herbert Diehl, Horst Bosche, Kurt Schneider and Heinz Kieczka Butanediols, Butenediol, and Butynediol" in Ullmann's Encyclopedia of Industrial Chemistry, 2000, Wiley-VCH, Weinheim. 〕
:2 CH2O + HC≡CH → HOCH2CCCH2OH
Several patented production methods use copper bismuth catalysts coated on an inert material. The normal temperature range for the reaction is 90 °C up to 150 °C, depending on the pressure used for the reaction which can range from 1 to 20 bar.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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