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・ 1-hydroxy-2-naphthoate 1,2-dioxygenase
・ 1-hydroxy-2-naphthoate hydroxylase
・ 1-Hydroxy-7-azabenzotriazole
・ 1-Hydroxycarotenoid 3,4-desaturase
・ 1-Hydroxyphenanthrene
・ 1-Hydroxypyrene
・ 1-Ichi
・ 1,4-Cycloheptadiene
・ 1,4-Cyclohexadiene
・ 1,4-Cyclohexanedione
・ 1,4-Diamino-2,3-dihydroanthraquinone
・ 1,4-Diazepine
・ 1,4-Dibromobenzene
・ 1,4-Dichloro-2-nitrobenzene
・ 1,4-Dichlorobenzene
1,4-Dichlorobut-2-ene
・ 1,4-dihydroxy-2-naphthoate polyprenyltransferase
・ 1,4-dihydroxy-2-naphthoyl-CoA hydrolase
・ 1,4-Dihydroxyanthraquinone
・ 1,4-Dimethoxybenzene
・ 1,4-Dioxane
・ 1,4-Dioxene
・ 1,4-Dioxin
・ 1,4-lactonase
・ 1,4-Naphthoquinone
・ 1,4-Thiazepine
・ 1,5-anhydro-D-fructose dehydratase
・ 1,5-anhydro-D-fructose reductase
・ 1,5-anhydro-D-fructose reductase (1,5-anhydro-D-mannitol-forming)
・ 1,5-Anhydroglucitol


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1,4-Dichlorobut-2-ene : ウィキペディア英語版
1,4-Dichlorobut-2-ene

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1,4-Dichlorobut-2-ene is a chlorinated butene. It is an intermediate in the industrial production of chloroprene, and the main impurity in technical grade chloroprene.〔.〕 The (''E'')-isomer is also one of the starting materials for Birman's total synthesis of the poriferic natural product sceptrin.〔. .〕
==Production of chloroprene==
Chloroprene is a monomer for the production of synthetic rubbers such as Neoprene. It is produced from butadiene in a three-step process. The first step is the liquid- or vapour-phase chlorination of butadiene to a mixture of 3,4-dichlorobut-1-ene and 1,4-dichlorobut-2-ene (both isomers). In the second step, the mixture of 1,4-dichlorobut-2-ene and 3,4-dichlorobut-1-ene is isomerized to pure 3,4-dichlorobut-1-ene by heating to temperatures of 60–120 °C in the presence of a catalyst. Finally, dehydrochlorination (elimination of hydrogen chloride) of 3,4-dichlorobut-1-ene with dilute sodium hydroxide solution in the presence of polymerization inhibitors gives crude chloroprene.〔. . 〕

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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