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・ 1,4-Cycloheptadiene
・ 1,4-Cyclohexadiene
・ 1,4-Cyclohexanedione
・ 1,4-Diamino-2,3-dihydroanthraquinone
・ 1,4-Diazepine
・ 1,4-Dibromobenzene
・ 1,4-Dichloro-2-nitrobenzene
・ 1,4-Dichlorobenzene
・ 1,4-Dichlorobut-2-ene
・ 1,4-dihydroxy-2-naphthoate polyprenyltransferase
・ 1,4-dihydroxy-2-naphthoyl-CoA hydrolase
・ 1,4-Dihydroxyanthraquinone
・ 1,4-Dimethoxybenzene
・ 1,4-Dioxane
・ 1,4-Dioxene
1,4-Dioxin
・ 1,4-lactonase
・ 1,4-Naphthoquinone
・ 1,4-Thiazepine
・ 1,5-anhydro-D-fructose dehydratase
・ 1,5-anhydro-D-fructose reductase
・ 1,5-anhydro-D-fructose reductase (1,5-anhydro-D-mannitol-forming)
・ 1,5-Anhydroglucitol
・ 1,5-Cyclooctadiene
・ 1,5-Diazabicyclo(4.3.0)non-5-ene
・ 1,5-Dihydroxynaphthalene
・ 1,5-Methano(10)annulene
・ 1,5-Pentanediol
・ 1,6-alpha-D-mannosidase
・ 1,6-alpha-L-fucosidase


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1,4-Dioxin : ウィキペディア英語版
1,4-Dioxin

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1,4-Dioxin (also referred as dioxin or ''p''-dioxin) is a heterocyclic, organic, non-aromatic〔Science of Synthesis: Houben-Weyl Methods of Molecular Transformations Vol. 16: Six-Membered Hetarenes with Two Identical Heteroatoms〕 compound with the chemical formula C4H4O2. There is an isomeric form of 1,4-dioxin, 1,2-dioxin (or ''o''-dioxin). 1,2-Dioxin is very unstable due to its peroxide-like characteristics.
The term “dioxin” is most commonly used for a family of derivatives of dioxin, known as polychlorinated dibenzodioxins (PCDDs).
==Preparation==
1,4-Dioxin can be prepared by cycloaddition, namely by the Diels–Alder reaction of furan and maleic anhydride. The adduct formed has a carbon-carbon double bond, which is converted to an epoxide. The epoxide then undergoes a retro-Diels–Alder reaction, forming 1,4-dioxin and regenerating maleic anhydride.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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