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1-octen-3-one : ウィキペディア英語版
Oct-1-en-3-one

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Oct-1-en-3-one (CH2=CHC(=O)(CH2)4CH3), also known as 1-octen-3-one, is the odorant that is responsible for the typical "metallic" smell of metals and blood coming into contact with skin.〔
〕 Oct-1-en-3-one has a strong metallic mushroom-like odor with an odor detection threshold of 0.03–1.12 µg/m3 and it is the main compound responsible for the "smell of metal", followed by decanal (smell: orange skin, flowery) and nonanal (smell: tallowy, fruity).〔(Supporting information for the Glindemann article )〕 Oct-1-en-3-one is the degradative reduction product of the chemical reaction of skin lipid peroxides and Fe2+. Skin lipid peroxides are formed from skin lipid by oxidation, either enzymatically by lipoxygenases or by air oxygen. Oct-1-en-3-one is a ketone analog of the alkene 1-octene.
== Natural occurrences ==
It is also produced by ''Uncinula necator'', a fungus that causes powdery mildew of grape.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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