翻訳と辞書
Words near each other
・ 18 Vayasu
・ 18 Vulpeculae
・ 18 Warriors of Sui-Tang Period
・ 18 Wheeler (band)
・ 18 wheeler (disambiguation)
・ 18 Wheels of Steel
・ 18 Years Later
・ 18 Years Old and Rising
・ 18 Yellow Roses
・ 18 éxitos de Franco De Vita
・ 18 – Allein unter Mädchen
・ 18" Mark 30 torpedo
・ 18+ (band)
・ 18,19-Dehydrobuprenorphine
・ 18-bit
18-Crown-6
・ 18-Electron rule
・ 18-Hydroxycorticosterone
・ 18-J
・ 18-Methoxycoronaridine
・ 18-Methylaminocoronaridine
・ 18-Norabietane
・ 18-point agreement
・ 18-pounder long gun
・ 18-pounder short gun
・ 18-Year-Old Virgin
・ 18...
・ 18.61
・ 180
・ 180 (2011 American film)


Dictionary Lists
翻訳と辞書 辞書検索 [ 開発暫定版 ]
スポンサード リンク

18-Crown-6 : ウィキペディア英語版
18-Crown-6

| Section2 =
| Section8 =
}}
18-Crown-6 is an organic compound with the formula ()6 and the IUPAC name of 1,4,7,10,13,16-hexaoxacyclooctadecane. It is a white, hygroscopic crystalline solid with a low melting point. Like other crown ethers, 18-crown-6 functions as a ligand for some metal cations with a particular affinity for potassium cations (binding constant in methanol: 106 M−1). The point group of 18-crown-6 is S6. The dipole moment of 18-crown-6 varies in different solvent and under different temperature. Under 25 °C, the dipole moment of 18-crown-6 is 2.76 ± 0.06 D in cyclohexane and 2.73 ± 0.02 in benzene. The synthesis of the crown ethers led to the awarding of the Nobel Prize in Chemistry to Charles J. Pedersen.
==Synthesis==
This compound is prepared by a modified Williamson ether synthesis in the presence of a templating cation: It can be also prepared by the oligomerization of ethylene oxide:〔
:(CH2OCH2CH2Cl)2 + (CH2OCH2CH2OH)2 + 2 KOH → (CH2CH2O)6 + 2 KCl + 2 H2O
It can be purified by distillation, where its tendency to supercool becomes evident. 18-Crown-6 can also be purified by recrystallisation from hot acetonitrile. It initially forms an insoluble solvate.〔 Rigorously dry material can be made by dissolving the compound in THF followed by the addition of NaK to give ()Na, an alkalide salt. Crystallographic analysis reveals a relatively flat molecule but one where the oxygen centres are not oriented in the idealized 6-fold symmetric geometry usually shown.〔J. D. Dunitz, P. Seiler "1,4,7,10,13,16-Hexaoxacyclooctadecane" Acta Cryst. (1974). B30, 2739. .〕 The molecule undergoes significant conformational change upon complexation.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
ウィキペディアで「18-Crown-6」の詳細全文を読む



スポンサード リンク
翻訳と辞書 : 翻訳のためのインターネットリソース

Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.