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| Section2 = | Section3 = }} 2,6-Xylidine is an aniline derivative with the chemical formula (CH3)2C6H3NH2. It is an isomer of 2,4-xylidine and 3,4-xylidine. It is a colourless liquid although commercial samples can appear to be yellow or even red. ==Production and reactions== Many xylidines are prepared by nitration of a xylene followed by hydrogenation of the nitroaromatic, but this approach is not efficient for this isomer. Instead, it is prepared from by treatment of the related xylenol with ammonia in the presence of oxide catalysts.〔M. Meyer "Xylidines" in Ullmann's Encylclopedia of Industrial Chemistry Wiley-VCH, Weinheim, 2012. 〕 2,6-Xylidine is a precursor to the anesthetic lidocaine: It is the precursor to the NHC ligand called Imes.〔Ison, E. A., Ison, A., "Synthesis of Well-Defined Copper N-Heterocyclic Carbene Complexes and Their Use as Catalysts for a "Click Reaction": A Multistep Experiment That Emphasizes the Role of Catalysis in Green Chemistry", Journal of Chemical Education 2012, volume 89, p. 1575. 〕 :450px 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「2,6-Xylidine」の詳細全文を読む スポンサード リンク
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