翻訳と辞書
Words near each other
・ 2-Methyltetrahydrofuran
・ 2-Methylundecanal
・ 2-millimeter band
・ 2-Naphthol
・ 2-Naphthylamine
・ 2-Nitroaniline
・ 2-Nitrobenzaldehyde
・ 2-Nitrochlorobenzene
・ 2-Nitrocinnamaldehyde
・ 2-Nitrodiphenylamine
・ 2-Nitrofluorene
・ 2-nitroimidazole nitrohydrolase
・ 2-Deoxystreptamine N-acetyl-D-glucosaminyltransferase
・ 2-Dimethylaminoethylazide
・ 2-Diphenylmethylpyrrolidine
2-Diphenylphosphinobenzaldehyde
・ 2-enoate reductase
・ 2-Epimerase
・ 2-EPT probability density function
・ 2-Ethoxybenzoic acid
・ 2-Ethoxyethanol
・ 2-Ethyl-1-butanol
・ 2-Ethyl-4,5-dimethylphenol
・ 2-Ethylanthraquinone
・ 2-Ethylhexanoic acid
・ 2-Ethylhexanol
・ 2-Ethylidene-1,5-dimethyl-3,3-diphenylpyrrolidine
・ 2-ethylmalate synthase
・ 2-EXPTIME
・ 2-factor theorem


Dictionary Lists
翻訳と辞書 辞書検索 [ 開発暫定版 ]
スポンサード リンク

2-Diphenylphosphinobenzaldehyde : ウィキペディア英語版
2-Diphenylphosphinobenzaldehyde

|Section2=
}}
2-Diphenylphosphinobenzaldehyde is an organophosphorus compound with the formula (C6H5)2PC6H4CHO. It is a yellow solid that dissolves in common organic solvents. The compound condenses with a variety of amines to give phosphine-imine and phosphine-amine ligands.〔S. J. Degrado, H. Mizutani and A. H. Hoveyda, "Modular Peptide-Based Phosphine Ligands in Asymmetric Catalysis: Efficient and Enantioselective Cu-Catalyzed Conjugate Additions to Five-, Six-, and Seven-Membered Cyclic Enones", J. Am. Chem. Soc. 2001, volume 123, pp. 755-756. 〕 It was first prepared by the reaction of chlorodiphenylphosphine with the Grignard reagent derived from the protected bromobenzaldehyde followed by deprotection.〔Schiemenz, Guenter P.; Kaack, Hermann "Aromatische Phosphine mit Substituenten zweiter Ordnung, XIII. Triarylphosphine mit mehreren Carbonyl-Funktionen durch Grignard-Synthese (Aromatic phosphines with second order substituents. XIII. Preparation of triarylphosphines with several carbonyl functions by Grignard synthesis)" Justus Liebigs Annalen der Chemie 1973, vol. 9, pp. 1480-93. . Hoots, J. E., Rauchfuss, T. B., Wrobleski, D. A. "Substituted Triaryl Phosphines" Inorganic Syntheses, 1982, Volume 21, pp. 175. 〕
==References==


抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
ウィキペディアで「2-Diphenylphosphinobenzaldehyde」の詳細全文を読む



スポンサード リンク
翻訳と辞書 : 翻訳のためのインターネットリソース

Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.