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・ 2-Methoxyethyl-18-methoxycoronaridinate
・ 2-Methoxypropene
・ 2-Methyl-1-butanol
・ 2-Methyl-1-pentanol
・ 2-Methyl-2,4-pentanediol
・ 2-Methyl-2-butene
・ 2-Methyl-2-heptanethiol
2-Methyl-2-nitrosopropane
・ 2-Methyl-2-pentanol
・ 2-Methyl-3-oxopropanoic acid
・ 2-Methyl-3-pentanol
・ 2-Methyl-3-phenylpiperidine
・ 2-Methyl-5-hydroxytryptamine
・ 2-Methyl-6-(phenylethynyl)pyridine
・ 2-Methyl-6-nitrobenzoic anhydride
・ 2-methyl-branched-chain-enoyl-CoA reductase
・ 2-Methyl-MDA
・ 2-Methylacetoacetyl-CoA
・ 2-methylacetoacetyl-CoA thiolase
・ 2-methylacyl-CoA dehydrogenase
・ 2-Methylbutyryl-CoA
・ 2-Methylbutyryl-CoA dehydrogenase deficiency


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2-Methyl-2-nitrosopropane : ウィキペディア英語版
2-Methyl-2-nitrosopropane

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2-Methyl-2-nitrosopropane (MNP or t-nitrosobutane) is the organic compound with the formula (CH3)3CNO. It is a blue liquid that is used in chemical research as a spin trap, i.e. it binds to radicals.
==Preparation and structure==
It is prepared by oxidation of (CH3)3CNH2 using hydrogen peroxide in the presence of sodium tungstate as a catalyst.〔A. Calder, A. R. Forrester, and S. P. Hepburn ''2-Methyl-2-nitrosopropane and Its Dimer'' Organic Syntheses, Coll. Vol. 6, p.803; Vol. 52, p.77. (Link )〕 The freshly distilled compound is a blue volatile liquid. Like other nitroso compounds, it features a bent C-N=O linkage. Upon standing at room temperature, the blue liquid converts to the colourless solid that is the dimer (m.p. 74-75 °C). In solution, this dimer quickly reverts to the blue monomer.〔


抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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