翻訳と辞書
Words near each other
・ 2-oxoglutarate/L-arginine monooxygenase/decarboxylase (succinate-forming)
・ 2-Oxohistidine
・ 2-oxoisovalerate dehydrogenase (acylating)
・ 2-oxopent-4-enoate hydratase
・ 2-Oxopent-4-enoic acid
・ 2-oxopropyl-CoM reductase (carboxylating)
・ 2-Pentanol
・ 2-Pentanone
・ 2-Pentyne
・ 2-Phenethyl propionate
・ 2-Phenyl-3,6-dimethylmorpholine
・ 2-Phenyl-3-aminobutane
・ 2-Phenylethylbromide
・ 2-Phenylhexane
・ 2-Phenylphenol
2-Phenylpyridine
・ 2-Phospho-L-lactate guanylyltransferase
・ 2-phospho-L-lactate transferase
・ 2-Phosphoglyceric acid
・ 2-phosphosulfolactate phosphatase
・ 2-Piperidinone
・ 2-plan project management software
・ 2-Polyprenyl-6-hydroxyphenyl methylase
・ 2-pop
・ 2-pounder gun
・ 2-Propanoyl-3-(4-isopropylphenyl)-tropane
・ 2-Pyridone
・ 2-Pyridone (data page)
・ 2-Pyridylethylamine
・ 2-Pyrone


Dictionary Lists
翻訳と辞書 辞書検索 [ 開発暫定版 ]
スポンサード リンク

2-Phenylpyridine : ウィキペディア英語版
2-Phenylpyridine

2-Phenylpyridine is an organic compound with the formula C6H5C5H4N. It is a colourless viscous liquid. The compound and related derivatives have attracted interest as precursors to highly fluorescent metal complexes of possible value as organic light emitting diodes (OLEDs).〔Zhou, Guijiang; Wong, Wai-Yeung; Yang, Xiaolong "New Design Tactics in OLEDs Using Functionalized 2-Phenylpyridine-Type Cyclometalates of Iridium(III) and Platinum(II)" Chemistry - An Asian Journal (2011), 6(7), 1706-1727. 〕
The compound is prepared by the reaction of phenyl lithium with pyridine:〔Evans, J. C. W.; Allen, C. F. H. "2-Phenylpyridine" Organic Syntheses (1938), vol. 18, p. 70. 〕
:C6H5Li + C5H5N → C6H5-C5H4N + LiH
The reaction of iridium trichloride with 2-phenylpyridine proceeds via cyclometallation to give the chloride-bridged complex:〔Lamansky, S., Djurovich, P., Murphy, D., Abdel-Razzaq, F., Kwong, R., Tsyba, I., Bortz, M., Mui, B., Bau, R., Thompson, M. E., "Synthesis and Characterization of Phosphorescent Cyclometalated Iridium Complexes", Inorganic Chemistry 2001, 40, 1704. 〕
:4 C6H5-C5H4N + 2 IrCl3(H2O)3 → Ir2Cl2(C6H4-C5H4N)4 + 4 HCl
This complex can be converted to the pictured tris(cyclometallated) derivative.
:
==References==


抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
ウィキペディアで「2-Phenylpyridine」の詳細全文を読む



スポンサード リンク
翻訳と辞書 : 翻訳のためのインターネットリソース

Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.