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2-naphthol : ウィキペディア英語版
2-Naphthol

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2-Naphthol, or β-naphthol, is a fluorescent colorless crystalline solid with the formula C10H7OH. It is an isomer of 1-naphthol, differing by the location of the hydroxyl group on the naphthalene ring. The naphthols are naphthalene homologues of phenol, but more reactive. Both isomers are soluble in simple alcohols, ethers, and chloroform. 2-Naphthol is a widely used intermediate for the production of dyes and other compounds.
==Production==
Traditionally, 2-naphthol is produced by a two-step process that begins with the sulfonation of naphthalene in sulfuric acid:〔Gerald Booth "Naphthalene Derivatives" in Ullmann's Encyclopedia of Industrial Chemistry, 2005, Wiley-VCH, Weinheim. .〕
:C10H8 + H2SO4 → C10H7SO3H + H2O
The sulfonic acid group is then cleaved in molten sodium hydroxide:
:C10H7(SO3H) + 3 NaOH → C10H7ONa + Na2SO3 + 2 H2O
Neutralization of the product with acid gives 2-naphthol.
2-Naphthol can also be produced by a method analogous to the cumene process.〔

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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