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2-nitrochlorobenzene : ウィキペディア英語版
2-Nitrochlorobenzene

2-Nitrochlorobenzene is an organic compound with the formula ClC6H4NO2.〔Gerald Booth, "Nitro Compounds, Aromatic" in ''Ullmann's Encyclopedia of Industrial Chemistry'', Wiley-VCH: Weinheim, 2005. 〕 It is a yellow crystalline solid that is important as a precursor to other compounds due to the two reactive sites present on the molecule.
==Synthesis==
Nitrochlorobenzene is typically synthesized by nitration of chlorobenzene in the presence of sulfuric acid:
:C6H5Cl + HNO3 → O2NC6H4Cl + H2O
This reaction affords a mixture of isomers. Using an acid ratio of 30/56/14, the product mix is typically 34-36% 2-nitrochlorobenzene and 63-65% 4-nitrochlorobenzene, with only about 1% 3-nitrochlorobenzene.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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