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2-nitrocinnamaldehyde : ウィキペディア英語版
2-Nitrocinnamaldehyde

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2-Nitrocinnamaldehyde, ''ortho''-nitrocinnamaldehyde or ''o''-nitrocinnamaldehyde is an organic aromatic compound containing a nitro group ortho- to the 1-position of cinnamaldehyde.
==Synthesis==

2-Nitrocinnamaldehyde can be synthesized by dissolving cinnamaldehyde to a solution of acetic anhydride in acetic acid, and adding a stoichiometric amount of concentrated nitric acid at 0–5 °C. Yields are around 36-46% of theoretical.
Nitration of cinnamaldehyde via acidification of a nitrate salt with H2SO4 also yields the ortho-nitro compound, however it also yields some of the para-nitro compound, which is generally undesired.
2-Nitrocinnamaldehyde can also be prepared by reacting 2-nitrobenzaldehyde with acetaldehyde in a condensation reaction.〔http://www.orgsyn.org/orgsyn/prep.asp?rxntypeid=181&prep=CV4P0722〕

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