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・ Acetobacter cerevisiae
・ Acetobacter fabarum
・ Acetobacter malorum
・ Acetobacter pomorum
・ Acetobacterium
・ Acetobacterium carbinolicum
・ Acetochlor
・ Acetofilamentum
・ Acetogen
・ Acetogenesis
・ Acetogenin
・ Acetoguanamine
・ Acetohalobium
・ Acetohexamide
・ Acetohydroxamic acid
Acetoin
・ Acetoin dehydrogenase
・ Acetoin racemase
・ Acetoin—ribose-5-phosphate transaldolase
・ Acetol
・ Acetolactate decarboxylase
・ Acetolactate synthase
・ Acetolactic acid
・ Acetolactone
・ Acetomicrobium
・ Acetone
・ Acetone (band)
・ Acetone (data page)
・ Acetone (disambiguation)
・ Acetone azine


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Acetoin : ウィキペディア英語版
Acetoin

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Acetoin, also known as 3-hydroxybutanone or acetyl methyl carbinol, with the molecular formula is C4H8O2, is a colorless or pale yellow to green yellow liquid with a pleasant, buttery odor. Acetoin is a chiral molecule. The form produced by bacteria is (R)-acetoin.〔Albert Gossauer: ''Struktur und Reaktivität der Biomoleküle'', Verlag Helvetica Chimica Acta, Zürich, 2006, Seite 285, ISBN 978-3-906390-29-1.〕
==Production in bacteria==
Acetoin is a neutral, four-carbon molecule used as an external energy store by a number of fermentive bacteria. It is produced by the decarboxylation of alpha-acetolactate, a common precursor in the biosynthesis of branched-chain amino acids. Owing to its neutral nature, production and excretion of acetoin during exponential growth prevents overacidification of the cytoplasm and the surrounding medium that would result from accumulation of acidic metabolic products, such as acetic acid and citric acid. Once superior carbon sources are exhausted, and the culture enters stationary phase, acetoin can be used to maintain the culture density. The conversion of acetoin into acetyl-CoA is catalysed by the acetoin dehydrogenase complex, following a mechanism largely analogous to the pyruvate dehydrogenase complex; however, as acetoin is not a 2-oxoacid, it does not undergo decarboxylation by the E1 enzyme; instead, a molecule of acetaldehyde is released.
In some bacteria, acetoin can also be reduced to 2,3-butanediol by acetoin reductase/2,3-butanediol dehydrogenase.
The Voges-Proskauer test is a commonly used microbiological test for acetoin production.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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