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|Section2= |Section3= }} Acetylferrocene is the organoiron compound with the formula (C5H5)Fe(C5H4COMe). It consists of ferrocene substituted by an acetyl group on one of the cyclopentadienyl rings. It is an orange, air-stable solid that is soluble in organic solvents. ==Preparation and reactions== Acetylferrocene is prepared by acetylation of ferrocene, usually with acetic anhydride: :(C5H5)2Fe + Ac2O → (C5H5)Fe(C5H4Ac) + AcOH The experiment is often used in the instructional laboratory to illustrate acylation as well as chromatographic separations.〔Donahue, C. J., Donahue, E. R., "Beyond Acetylferrocene: The Synthesis and NMR Spectra of a Series of Alkanoylferrocene Derivatives", Journal of Chemical Education 2013, volume 90, pp. 1688. 〕 Acetylferrocene can be converted to many derivatives, e.g., reduction to the chiral alcohol (C5H5)Fe(C5H4CH(OH)Me). The oxidized derivative, acetylferrocenium, is used as a 1e-oxidant in the research laboratory.〔Connelly, N. G., Geiger, W. E., "Chemical Redox Agents for Organometallic Chemistry", Chem. Rev. 1996, 96, 877. 〕 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Acetylferrocene」の詳細全文を読む スポンサード リンク
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