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Bacillithiol : ウィキペディア英語版
Bacillithiol

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Bacillithiol (BSH or Cys-GlcN-mal) is a thiol compound found in ''Bacillus'' species. It is likely involved in maintaining cellular redox balance and plays a role in microbial resistance to the antibiotic fosfomycin.
==Structure==
Chemically, it is a glycoside formed between L-cysteinyl-D-glucosamine and malic acid. It was isolated and identified (as its bacillithiol-S-bimane derivative) in 2009 from ''Staphylococcus aureus'' and ''Deinococcus radiodurans'',〔 although it was first detected in 2007, as an unidentified thiol in ''Bacillus anthracis''. The naturally occurring free thiol form of bacillithiol has since been synthesised and characterised along with its biosynthetic precursors and its symmetrical disulfide.

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