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Baotite
Baotite Ba4Ti4(Ti, Nb, Fe)4(Si4O12)O16Cl is a rare mineral recognized as having a unique four-fold silicate ring.〔Chakhmouradian, A.R. and Mitchell, R.H. (2002) The mineralogy of Ba- and Zr-rich alkaline pegmatites from Gordon Butte, Crazy Mountains (Montana, USA): comparisons between potassic and sodic agpaitic pegmatites. Contributions to Mineralogy and Petrography, 143, 93-114.〕 Crystals are tetragonal, though commonly deformed to the extent of appearing monoclinic. Named for the locality of first discovery, Baotou, China, baotite has been found in hydrothermal veins and alkalic rocks in various locations around the world. ==Structure== Simonov first determined the crystal structure of baotite in which (Ti, Nb, Fe)-octahedra share edges, forming chains and cross-linking at the corners forming a 4-fold screw axis in the (001); these columns are analogous to those in rutile.〔Simonov, V.I. (1960) Baotite, a mineral with a metasillicate ring (Si4O12). Kristallografiya, 5, 544-546 (in Russian). Abs. in American Mineralogist, 46, 466, 1961.〕 Four silicate tetrahedra share corners creating characteristic rings in the plane perpendicular to the c axis.〔Shinno, I. and Li, Z. (1998) Mössbauer studies of baotite and bafertisite. Hyperfine Interactions, 116, 189-196.〕 The barium cation is between the rings and rutile columns, while chloride fills the void between each pair of rings.〔Cooper, A.F. (1996) Nb-rich baotite in carbonatites and fenites at Haast River, New Zealand. Mineralogical Magazine, 60, 473-482.〕 Chlorine’s presence is not necessary for the structure to balance electrostatically.
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