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A non-Kekulé molecule is a conjugated hydrocarbon that cannot be assigned a classical Kekulé structure. Since non-Kekulé molecules have two or more formal radical centers, their spin-spin interactions can cause electrical conductivity or ferromagnetism (molecule-based magnets), and applications to functional materials are expected. However, as these molecules are quite reactive and most of them are easily decomposed or polymerized at room temperature, strategies for stabilization are needed for their practical use. Synthesis and observation of these reactive molecules are generally accomplished by matrix-isolation methods. ==Biradicals== The simplest non-Kekulé molecules are biradicals. A biradical is an even-electron chemical compound with two free radical centres which act ''independently'' of each other. They should not be confused with the more general class of diradicals.〔 One of the first biradicals was synthesized by Wilhelm Schlenk in 1915 following the same methodology as Moses Gomberg's triphenylmethyl radical. The so-called Schlenk-Brauns hydrocarbons are:〔 Eugene Müller, with the aid of a Gouy balance, established for the first time that these compounds are paramagnetic with a triplet ground state. Another classic biradical was synthesised by Tschitschibabin in 1907.〔〔 Other classical examples are the biradicals described by Yang in 1960〔 and by Coppinger in 1962.〔〔〔 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Non-Kekulé molecule」の詳細全文を読む スポンサード リンク
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