翻訳と辞書 |
Bis(cyclooctatetraene)iron : ウィキペディア英語版 | Bis(cyclooctatetraene)iron
Bis(cyclooctatetraene)iron is an organoiron compound with the formula Fe(C8H8)2, abbreviated Fe(COT)2. It is an air sensitive black solid that is soluble in diethyl ether and aromatic solvents. The compound decomposes in solution after a few days even under inert atmosphere.〔Gerlach, D. H., Schunn, R. A. "Bis(1,3,5,7-cyclooctatetraene)iron(0)," Inorganic Syntheses, 1974, volume 15, pp. 1-4. 〕 It has no practical applications but has been studied as soluble source of Fe(0). ==Preparation== The laboratory synthesis of Fe(COT)2, using Schlenk techniques, involves reduction of ferric acetylacetonate by triethylaluminium in the presence of 1,3,5,7-cyclooctatetraene:〔 :Fe(C5H7O2)3 + 2 C8H8 + 3 Al(C2H5)3 → Fe(C8H8)2 + 3 Al(C2H5)2(C5H7O2) + 3/2 C2H4 + 3/2 C2H6
抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Bis(cyclooctatetraene)iron」の詳細全文を読む
スポンサード リンク
翻訳と辞書 : 翻訳のためのインターネットリソース |
Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.
|
|