翻訳と辞書 Words near each other ・ Biscari massacre ・ Biscarrosse ・ Biscarrosse – Parentis Airport ・ Biscarrués ・ Biscathorpe ・ Bis(5'-nucleosyl)-tetraphosphatase (asymmetrical) ・ Bis(5'-nucleosyl)-tetraphosphatase (symmetrical) ・ Bis(benzene)chromium ・ Bis(chloroethyl) ether ・ Bis(chloromethyl) ether ・ Bis(chloromethyl) ketone ・ Bis(chloromethyl)benzene ・ Bis(cyclooctadiene)nickel(0) ・ Bis(cyclooctatetraene)iron ・ Bis(dicyclohexylphosphino)ethane ・ Bis(dinitrogen)bis(1,2-bis(diphenylphosphino)ethane)molybdenum(0) ・ Bis(pinacolato)diboron ・ Bis(pyridine)iodonium(I) tetrafluoroborate ・ Bis(triethoxysilylpropyl)tetrasulfide ・ Bis(trimethylsilyl)acetamide ・ Bis(trimethylsilyl)acetylene ・ Bis(trimethylsilyl)amine ・ Bis(trimethylsilyl)mercury ・ Bis(trimethylsilyl)sulfide ・ Bis(triphenylphosphine)iminium chloride ・ Bis(triphenylphosphine)nickel chloride ・ Bis(triphenylphosphine)palladium(II) dichloride ・ Bis(triphenylphosphine)platinum chloride ・ Bis-(2,4,5-trichloro-6-(pentyloxycarbonyl)phenyl)oxalate ・ Bis-choline tetrathiomolybdate Dictionary Lists mini英和辞書 mini和英辞書 Webster 1913 Latin-English FOLDOC Wikipedia English ウィキペディア

翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Bis(dinitrogen)bis(1,2-bis(diphenylphosphino)ethane)molybdenum(0) ： ウィキペディア英語版 Bis(dinitrogen)bis(1,2-bis(diphenylphosphino)ethane)molybdenum(0) |Section7= }} ''trans''-Bis(dinitrogen)bis()molybdenum(0) is a coordination complex with the formula Mo(N2)2(dppe)2. It is a relatively air stable yellow-orange solid. It is notable as being the first dinitrogen containing complex of molybdenum.〔 ==Structure== Mo(N2)2(dppe)2 is an octahedral complex with idealized D4h point group symmetry. The dinitrogen ligands are mutually trans across the metal center. The Mo-N bond has a length of 2.01Å, and the N-N bond has a length of 1.10Å.〔Uchida, T; Uchida, Y; Hidai, M; Kodama, T. The Crystal and Molecular Structure of trans-Bis(dinitrogen)bis()molybdenum(0). Bull. Chem. Soc. Jpn. 1971, 44, 2883. 〕 This length is close to the free nitrogen bond length, but coordination to the metal weakens the N-N bond making it susceptible to electrophilic attack.〔Hidai, M; Yasuchi, M. Chemical Transformations of Coordinated Dinitrogen in Molybdenum and Tungsten Phosphine Complexes. ACS symposium series. 1993, 535, 346. 〕 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Bis(dinitrogen)bis(1,2-bis(diphenylphosphino)ethane)molybdenum(0)」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.