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Bis(pinacolato)diboron : ウィキペディア英語版 | Bis(pinacolato)diboron
|Section2= |Section3= }} Bis(pinacolato)diboron is a boron containing two pinacolato ligands. With the formula ()2, it is a colourless solid that is soluble in organic solvents. It is a commercially available reagent for making pinacol boronic esters for organic synthesis. ==Preparation and structure== This compound may be prepared by reacting tetrakis(dimethylamino)diboron with pinacol in acidic conditions. The B-B bond distance is 1.711(6) Å.〔C.Kleeberg, A.G.Crawford, A.S.Batsanov, P.Hodgkinson, D.C.Apperley, Man Sing Cheung, Zhenyang Lin, T.B.Marder "Spectroscopic and Structural Characterization of the CyNHC Adduct of B2pin2 in Solution and in the Solid State" ''J. Org. Chem'' 2012, vol. 77, pp. 785. 〕
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