翻訳と辞書 Words near each other ・ Biscathorpe ・ Bis(5'-nucleosyl)-tetraphosphatase (asymmetrical) ・ Bis(5'-nucleosyl)-tetraphosphatase (symmetrical) ・ Bis(benzene)chromium ・ Bis(chloroethyl) ether ・ Bis(chloromethyl) ether ・ Bis(chloromethyl) ketone ・ Bis(chloromethyl)benzene ・ Bis(cyclooctadiene)nickel(0) ・ Bis(cyclooctatetraene)iron ・ Bis(dicyclohexylphosphino)ethane ・ Bis(dinitrogen)bis(1,2-bis(diphenylphosphino)ethane)molybdenum(0) ・ Bis(pinacolato)diboron ・ Bis(pyridine)iodonium(I) tetrafluoroborate ・ Bis(triethoxysilylpropyl)tetrasulfide ・ Bis(trimethylsilyl)acetamide ・ Bis(trimethylsilyl)acetylene ・ Bis(trimethylsilyl)amine ・ Bis(trimethylsilyl)mercury ・ Bis(trimethylsilyl)sulfide ・ Bis(triphenylphosphine)iminium chloride ・ Bis(triphenylphosphine)nickel chloride ・ Bis(triphenylphosphine)palladium(II) dichloride ・ Bis(triphenylphosphine)platinum chloride ・ Bis-(2,4,5-trichloro-6-(pentyloxycarbonyl)phenyl)oxalate ・ Bis-choline tetrathiomolybdate ・ Bis-gamma-glutamylcystine reductase ・ Bis-HPPP ・ Bis-peptide ・ Bis-quits Dictionary Lists mini英和辞書 mini和英辞書 Webster 1913 Latin-English FOLDOC Wikipedia English ウィキペディア

翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Bis(trimethylsilyl)acetamide ： ウィキペディア英語版 Bis(trimethylsilyl)acetamide |Section2= |Section7= |Section8= }} Bis(trimethylsilyl)acetamide (BSA) is an organosilicon compound with the formula Me3SiNC(OSiMe3)Me (Me = CH3). It is a colorless liquid that is soluble in diverse organic solvents, but reacts rapidly with compounds, including solvents and moisture, containing OH and NH functional groups. It is used in analytical chemistry for the derivatisation of compounds in analysis to increase their volatility, e.g. for gas chromatography. It is also used to introduce the trimethylsilyl protecting group in organic synthesis.〔Harry Heaney, Jian Cui, “N,O-Bis(trimethylsilyl)acetamide” Encyclopedia of Reagents for Organic Synthesis Copyright © 2007 John Wiley & Sons. .〕 A related reagent is N,O-bis(trimethylsilyl)trifluoroacetamide (BSTFA). ==Synthesis and reactions== BSA is prepared by treating acetamide with trimethylsilyl chloride in the presence of a base:〔 : 2 Me3SiCl + H2NC(O)Me + 2 Et3N → Me3SiNC(OSiMe3)Me + 2 Et3NHCl The reaction of BSA with alcohols gives the corresponding trimethylsilyl ether, together with N-(trimethylsilyl)acetamide as a byproduct: :ROH + Me3SiNC(OSiMe3)Me → Me3SiN(H)C(O)Me + ROSiMe3 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Bis(trimethylsilyl)acetamide」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.