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・ Bis(chloroethyl) ether
・ Bis(chloromethyl) ether
・ Bis(chloromethyl) ketone
・ Bis(chloromethyl)benzene
・ Bis(cyclooctadiene)nickel(0)
・ Bis(cyclooctatetraene)iron
・ Bis(dicyclohexylphosphino)ethane
・ Bis(dinitrogen)bis(1,2-bis(diphenylphosphino)ethane)molybdenum(0)
・ Bis(pinacolato)diboron
・ Bis(pyridine)iodonium(I) tetrafluoroborate
・ Bis(triethoxysilylpropyl)tetrasulfide
・ Bis(trimethylsilyl)acetamide
・ Bis(trimethylsilyl)acetylene
・ Bis(trimethylsilyl)amine
・ Bis(trimethylsilyl)mercury
Bis(trimethylsilyl)sulfide
・ Bis(triphenylphosphine)iminium chloride
・ Bis(triphenylphosphine)nickel chloride
・ Bis(triphenylphosphine)palladium(II) dichloride
・ Bis(triphenylphosphine)platinum chloride
・ Bis-(2,4,5-trichloro-6-(pentyloxycarbonyl)phenyl)oxalate
・ Bis-choline tetrathiomolybdate
・ Bis-gamma-glutamylcystine reductase
・ Bis-HPPP
・ Bis-peptide
・ Bis-quits
・ Bis-TOM
・ Bis-tris methane
・ Bis-tris propane
・ Bisa


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Bis(trimethylsilyl)sulfide : ウィキペディア英語版
Bis(trimethylsilyl)sulfide

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Bis(trimethylsilyl) sulfide is the chemical compound with the formula ((CH3)3Si)2S. Often abbreviated (tms)2S, this colourless, vile-smelling liquid is a useful aprotic source of “S2−“ in chemical synthesis.
==Synthesis==
The reagent is prepared by treating trimethylsilyl chloride with anhydrous sodium sulfide:
:2 (CH3)3SiCl + Na2S → ((CH3)3Si)2S + 2 NaCl
((CH3)3Si)2S must be protected from air because it hydrolyzes readily:
:((CH3)3Si)2S + H2O → ((CH3)3Si)2O + H2S

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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