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・ Bromocriptine
・ Bromocyclohexane
・ Bromocyclopentane
・ Bromodeoxyuridine
・ Bromoderma
・ Bromodichloromethane
・ Bromodifluoroacetyl chloride
・ Bromodifluoromethane
・ Bromodiphenylmethane
・ Bromodomain
・ Bromodomain and WD repeat-containing protein 1
・ Bromodomain and WD repeat-containing protein 3
・ Bromodomain-containing protein 3
・ Bromoethane
・ Bromofluorocarbon
Bromofluoromethane
・ Bromoform
・ Bromoform (data page)
・ Bromoil Process
・ Bromoiodomethane
・ Bromomethane
・ Bromont
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・ Bromont municipal election, 2009
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・ Bromont-Lamothe
・ Bromopentaamminecobalt(III) bromide
・ Bromopentacarbonylrhenium(I)


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Bromofluoromethane : ウィキペディア英語版
Bromofluoromethane

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Bromofluoromethane is a mixed gaseous halomethane soluble in alcohol and very soluble in chloroform.
Its standard molar entropy, ''S''ogas is 276.3 J/(mol K) and heat capacity, ''cp'' is 49.2 J/(mol K).
== Preparation ==
Up to date, it has been prepared by three prevailingly ineffective methods:
# From salts of fluoroacetic acid using a Hunsdiecker type of reaction.
# From dibromofluoromethane by reductive debromination with a Swarts reagent.
# From a dihalomethane by an halogen exchange reaction or from a halomethane by catalyzed bromination or fluorination.
The method with the highest yield is reductive debromination of dibromofluoromethane using an organotin hydride.〔(Debrominating dibromofluoromethane with tributyltin hydride )〕

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
ウィキペディアで「Bromofluoromethane」の詳細全文を読む



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