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Bromopentacarbonylrhenium(I) : ウィキペディア英語版 | Bromopentacarbonylrhenium(I)
|Section2= |Section3= }} Bromopentacarbonylrhenium(I) is an inorganic compound of rhenium, commonly used for the syntheses of other rhenium complexes. ==Preparation== Bromopentacarbonylrhenium(I) is commercially available. It is also easily and inexpensively synthesized by the oxidation of dirhenium decacarbonyl with bromine: :Re2(CO)10 + Br2 → 2 ReBr(CO)5 It was first prepared by the "reductive carbonylation" of rhenium(III) bromide: :ReBr3 + 2 Cu + 5 CO → BrRe(CO)5 + 2 CuBr Copper(I) bromide is a byproduct.
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