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Bromopentacarbonylrhenium(I)
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Bromopentacarbonylrhenium(I) : ウィキペディア英語版
Bromopentacarbonylrhenium(I)

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Bromopentacarbonylrhenium(I) is an inorganic compound of rhenium, commonly used for the syntheses of other rhenium complexes.
==Preparation==
Bromopentacarbonylrhenium(I) is commercially available. It is also easily and inexpensively synthesized by the oxidation of dirhenium decacarbonyl with bromine:
:Re2(CO)10 + Br2 → 2 ReBr(CO)5
It was first prepared by the "reductive carbonylation" of rhenium(III) bromide:
:ReBr3 + 2 Cu + 5 CO → BrRe(CO)5 + 2 CuBr
Copper(I) bromide is a byproduct.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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