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・ Carbadox
・ Carbajal
・ Carbajales de Alba
・ Carbajo
・ Carbajosa de la Sagrada
・ Carbaldrate
・ Carbalia
・ Carballeda
・ Carballeda de Avia
・ Carballeda de Valdeorras
・ Carballedo
・ Carballo
・ Carballo (disambiguation)
・ Carballo (name)
・ Carballo (Narcea)
Carbamate
・ Carbamate kinase
・ Carbamazepine
・ Carbamic acid
・ Carbamino
・ Carbaminohemoglobin
・ Carbamoyl aspartic acid
・ Carbamoyl chloride
・ Carbamoyl phosphate
・ Carbamoyl phosphate synthase II
・ Carbamoyl phosphate synthetase
・ Carbamoyl phosphate synthetase I
・ Carbamoyl phosphate synthetase I deficiency
・ Carbamoyl-serine ammonia-lyase
・ Carbanak


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Carbamate : ウィキペディア英語版
Carbamate

A carbamate is an organic compound derived from carbamic acid (NH2COOH). A carbamate group, carbamate ester (e.g., ethyl carbamate), and carbamic acids are functional groups that are inter-related structurally and often are interconverted chemically. Carbamate esters are also called urethanes.
==Synthesis==
Carbamic acids are derived from amines:
:R2NH + CO2 → R2NCO2H
Carbamic acid is about as acidic as acetic acid. Ionization of a proton gives the carbamate anion, the conjugate base of carbamic acid:
:R2NCO2H → R2NCO2 + H+
Carbamates also arise via hydrolysis of chloroformamides and subsequent esterification:
:R2NC(O)Cl + H2O → R2NCO2H + HCl
Carbamates may be formed from the Curtius Rearrangement, where isocyanates formed are reacted with an alcohol.
:RNCO + R'OH → RNHCO2R'

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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