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・ Chloritoid
・ Chlormadinone
・ Chlormadinone acetate
・ Chlormayenite
・ Chlormephos
・ Chlormequat
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・ Chlormethine
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・ Chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium
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Chloro(pyridine)cobaloxime
・ Chloro(tetrahydrothiophene)gold(I)
・ Chloro(triphenylphosphine)gold(I)
・ Chloro-5-substituted adamantyl-1,2-dioxetane phosphate
・ Chloroacetaldehyde
・ Chloroacetamide
・ Chloroacetic acid
・ Chloroacetic acids
・ Chloroacetone
・ Chloroacetyl chloride
・ Chloroalkyl ether
・ Chloroauric acid
・ Chlorobaptella
・ Chlorobenzene
・ Chlorobenzene (data page)


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Chloro(pyridine)cobaloxime : ウィキペディア英語版
Chloro(pyridine)cobaloxime

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Chloro(pyridine)cobaloxime is a coordination compound containing a CoIII center with octahedral coordination. It has long been considered as a model compound of vitamin B12 for studying the properties and mechanism of action of the vitamin. It belongs to a class of bis(dimethylglyoximato)cobalt(III) complexes with different axial ligands, called cobaloximes.
==Structure==

The compound consists of a distorted octahedral CoIII center ligated by two dimethylglyoxime molecules in the equatorial plane, as well as a chloride ion and a pyridine molecule coordinating to the cobalt center at the axial position. Crystallographic data supports that the coplanar dimethylgoxime molecules make dihedral angles of less than 3o. In addition, the axial distance between the cobalt and the chloride ion was determined to be 2.229 Å and the distance between the cobalt and the pyridine to be 1.959 Å.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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