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|Section2= |Section3= }} Chloro(triphenylphosphine)gold(I) is the coordination complex with the formula (Ph3P)AuCl. This colorless solid is the complex of triphenylphosphine and gold(I) chloride. ==Preparation and structure== The complex is prepared by reducing chloroauric acid with triphenylphosphine in 95% ethanol:〔Pierre Braunstein, Hans Lehner, Dominique Matt "A Platinum-Gold Cluster: Chloro-1κCl-Bis(Triethylphosphine-1κP)Bis(Triphenyl- Phosphine)-2κP, 3κP-Triangulo- Digold-Platinum(1 +) Trifluoromethanesulfonate" Inorganic Syntheses, 1990, Volume 27, Pages 218–221. 〕 :HAuCl4 + H2O + 2 PPh3 → (Ph3P)AuCl + Ph3PO + 3 HCl The complex adopts a linear coordination geometry, which is typical of most gold(I) compounds. 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Chloro(triphenylphosphine)gold(I)」の詳細全文を読む スポンサード リンク
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