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・ Chlormadinone acetate
・ Chlormayenite
・ Chlormephos
・ Chlormequat
・ Chlormerodrin
・ Chlormethine
・ Chlormezanone
・ Chlormidazole
・ Chlormint
・ Chlornaltrexamine
・ Chlornaphazine
・ Chloro(cyclopentadienyl)bis(triphenylphosphine)ruthenium
・ Chloro(dimethyl sulfide)gold(I)
・ Chloro(pyridine)cobaloxime
・ Chloro(tetrahydrothiophene)gold(I)
Chloro(triphenylphosphine)gold(I)
・ Chloro-5-substituted adamantyl-1,2-dioxetane phosphate
・ Chloroacetaldehyde
・ Chloroacetamide
・ Chloroacetic acid
・ Chloroacetic acids
・ Chloroacetone
・ Chloroacetyl chloride
・ Chloroalkyl ether
・ Chloroauric acid
・ Chlorobaptella
・ Chlorobenzene
・ Chlorobenzene (data page)
・ Chlorobenzilate
・ Chlorobenzoic acid


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Chloro(triphenylphosphine)gold(I) : ウィキペディア英語版
Chloro(triphenylphosphine)gold(I)

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Chloro(triphenylphosphine)gold(I) is the coordination complex with the formula (Ph3P)AuCl. This colorless solid is the complex of triphenylphosphine and gold(I) chloride.
==Preparation and structure==
The complex is prepared by reducing chloroauric acid with triphenylphosphine in 95% ethanol:〔Pierre Braunstein, Hans Lehner, Dominique Matt "A Platinum-Gold Cluster: Chloro-1κCl-Bis(Triethylphosphine-1κP)Bis(Triphenyl- Phosphine)-2κP, 3κP-Triangulo- Digold-Platinum(1 +) Trifluoromethanesulfonate" Inorganic Syntheses, 1990, Volume 27, Pages 218–221. 〕
:HAuCl4 + H2O + 2 PPh3 → (Ph3P)AuCl + Ph3PO + 3 HCl
The complex adopts a linear coordination geometry, which is typical of most gold(I) compounds.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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