|
|Section2= |Section3= }} 2-Cyclopentenone is a hydrocarbon with chemical formula 56 and CAS number 930-30-3. It is structurally similar to cyclopentanone, with the additional feature of α-β unsaturation in the ring system. 2-Cyclopentenone belongs to the cycloalkene (alkenes which have one or more rings of carbon atoms) class of compounds and is also a ketone (it possesses a carbonyl functional group). It is a liquid at room temperature with a boiling point of 150 °C. It has been isolated from pressure-cooked pork liver by simultaneous steam distillation and continuous solvent extraction. The term cyclopentenone may also refer to a structural motif wherein the cyclopentenone moiety is a subsection of a larger molecule. In this regard, cyclopentenones are found in a large number of natural products, including jasmone, the aflatoxins, and several prostaglandins. ==Synthesis== 2-Cyclopentenones can be synthesized in a number of ways. Industrially, the most common procedures are elimination of α-bromo-cyclopentanone using lithium carbonate and Claisen condensation-decarboxylation-isomerization cascades of unsaturated diesters as shown below. As a functional group, the synthesis of 2-cyclopentenones is accomplished in a variety of other ways, including the Nazarov cyclization reaction from divinyl ketones, Saegusa–Ito oxidation from cyclopentanones, ring-closing metathesis from the corresponding dienes, oxidation of the corresponding cyclic allylic alcohols, and the Pauson–Khand reaction from alkenes, alkynes, and carbon monoxide. 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Cyclopentenone」の詳細全文を読む スポンサード リンク
|