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Cyclotriveratrylene : ウィキペディア英語版 | Cyclotriveratrylene
Cyclotriveratrylene (CTV) is an organic compound with the formula ()3. It is a white solid that is soluble in organic solvents. The compound is a macrocycle and used in host-guest chemistry as a molecular host. ==Synthesis== The compound can be synthesised from veratrole alcohol upon acid catalysis. :Cyclotriveratrylene synthesis Operating via the same intermediates, an alternative synthesis involves the acid-catalyzed reaction of veratrole and formaldehyde. The method is similar to the reactions that give phenol formaldehyde resins except that the degree of polymerization is moderated by the methoxy substituents.〔Collet, A., "Cyclotriveratrylenes and cryptophanes", Tetrahedron 1987, vol. 43, 5725.〕
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