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DPEN : ウィキペディア英語版
Diphenylethylenediamine

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1,2-Diphenyl-1,2-ethylenediamine is an organic compound with the formula H2NCHPhCHPhNH2, where Ph is C6H5, phenyl. This diamine is a precursor to a ligand for certain homogeneous hydrogenation catalysts. It can be prepared from benzil by reductive amination.
==Optical resolution==
DPEN can be obtained as both the chiral and meso diastereomers, depending on the relative stereochemistry of the two CHPhNH2 subunits. The chiral diastereomer, which is of greater value, can be resolved into the R,R- and S,S- enantiomers using tartaric acid as the resolving agent. In methanol, the R,R enantiomer has an specific rotation of ()23 +106±1°.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
ウィキペディアで「Diphenylethylenediamine」の詳細全文を読む



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