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De-icing is defined as removal of snow, ice or frost from a surface. Anti-icing is understood to be the application of chemicals that not only de-ice, but also remain on a surface and continue to delay the reformation of ice for a certain period of time, or prevent adhesion of ice to make mechanical removal easier. == Approaches == De-icing can be accomplished by mechanical methods (scraping, pushing); through the application of heat; by use of dry or liquid chemicals designed to lower the freezing point of water (various salts or brines, alcohols, glycols); or by a combination of these different techniques. Anti-icing of aircraft is accomplished by applying a protective layer, using a viscous fluid called anti-ice fluid, over a surface to absorb the contaminate. All anti-ice fluids offer only limited protection, dependent upon frozen contaminant type and prevailing weather conditions. A fluid has failed when it no longer can absorb the contaminant and it essentially becomes a contaminant itself. Even water can be a contaminant in this sense, as it dilutes the anti-icing agent until it is no longer effective. De-icing of roads has traditionally been done with salt, spread by snowplows or dump trucks designed to spread it, often mixed with sand and gravel, on slick roads. Sodium chloride (rock salt) is normally used, as it is inexpensive and readily available in large quantities. However, since salt water still freezes at , it is of no help when the temperature falls below this point. It also has a strong tendency to cause corrosion, rusting the steel used in most vehicles and the rebar in concrete bridges. Depending on the concentration, it can be toxic to some plants and animals, and some urban areas have moved away from it as a result. More recent snowmelters use other salts, such as calcium chloride and magnesium chloride, which not only depress the freezing point of water to a much lower temperature, but also produce an exothermic reaction. They are somewhat safer for sidewalks, but excess should still be removed. More recently, organic compounds have been developed that reduce the environmental issues connected with salts and have longer residual effects when spread on roadways, usually in conjunction with salt brines or solids. These compounds are generated as byproducts of agricultural operations such as sugar beet refining or the distillation process that produces ethanol. Additionally, mixing common rock salt with some of the organic compounds and magnesium chloride results in spreadable materials that are both effective to much colder temperatures () as well as at lower overall rates of spreading per unit area.〔()〕 Direct infrared heating has also been proposed for deicing purpose. This heat transfer mechanism is substantially faster than conventional heat transfer modes used by conventional deicing (convection and conduction) due to the cooling effect of the air on the deicing fluid spray. Solar road systems have been used to maintain the surface of roads above the freezing point of water. An array of pipes embedded in the road surface is used to collect solar energy in summer, transfer the heat to thermal banks and return the heat to the road in winter to maintain the surface above .〔(【引用サイトリンク】 Thermal Energy Storage in ThermalBanks for under runway heating )〕 This automated form of renewable energy collection, storage and delivery avoids the environmental issues of using chemical contaminants. It has been suggested recently that superhydrophobic surfaces capable to repel water can also be used to prevent ice accumulation leading to the icephobicity. However, not every superhydrophobic surface is icephobic 〔 〕 and the method is still under development 〔 〕 In particular, the ice/frost formation over the entire superhydrophobic surface is inevitable as a result of undesired inter-droplet freezing wave propagation initiated by the sample edges. Moreover, the frost formation directly results in an increased frost adhesion, posing severe challenges for the subsequent defrosting process. By creating hierarchical surface, the interdroplet freezing wave propagation can be suppressed whereas the ice/frost removal can be promoted. The enhanced performances are mainly owing to the activation of the microscale edge effect in the hierarchical surface, which increases the energy barrier for ice bridging as well as engendering the liquid lubrication during the deicing/defrosting process.〔Xuemei Chen Ruiyuan Ma, Hongbo Zhou, Xiaofeng Zhou, Lufeng Che, Shuhuai Yao, Zuankai Wang. Activating the microscale edge effect in a hierarchical surface for frosting suppression and defrosting promotion, Scientific Reports, 3,2515 (2013) 〕 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「De-ice」の詳細全文を読む スポンサード リンク
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