翻訳と辞書
Words near each other
・ Dehydroamino acid
・ Dehydroascorbic acid
・ Dehydrocholic acid
・ Dehydrocorybulbine
・ Dehydrocurvularin
・ Dehydrodolichyl diphosphate synthase
・ Dehydroemetine
・ Dehydroepiandrosterone
・ Dehydroepiandrosterone sulfate
・ Dehydrogenase
・ Dehydrogenation
・ Dehydrogenation of amine-boranes
・ Dehydrogenative coupling of silanes
・ Dehydrogluconate dehydrogenase
・ Dehydrogluconokinase
Dehydrohalogenation
・ Dehydrohexahydroxydiphenic acid
・ Dehydronorketamine
・ Dehydroretinal
・ Dehydrosecodine
・ Dehyur
・ Dehzanun
・ Dehzir-e Dudera
・ DEI
・ Dei District
・ Dei Filius
・ Dei gesta per Francos
・ Dei Gratia (brigantine)
・ Dei Gratia Regina
・ Dei Hamo


Dictionary Lists
翻訳と辞書 辞書検索 [ 開発暫定版 ]
スポンサード リンク

Dehydrohalogenation : ウィキペディア英語版
Dehydrohalogenation

Dehydrohalogenation is an organic reaction in which alkyl halide when boiled with alcoholic alkali gives corresponding alkene. It is also called a β-Elimination reaction and is a type of elimination reaction.
In this reaction, the halogen on the carbon in the alkyl halide reacts with hydrogen present on the β-carbon releasing hydrogen halide. Hence an alkene is formed due to formation of a double bond between the α- and β-carbon. Zaitsev's rule helps to explain regioselectivity for this reaction type. The opposite transformation is called hydrohalogenation.
==Reactions==
File:Beta elimination.svg
Here ethyl chloride reacts with potassium hydroxide dissolved in ethanol, giving ethene. Likewise, 1-chloropropane and 2-chloropropane give propene.
Chlorobenzene does not react with potassium hydroxide due to the presence of the benzene ring, which, due to stabilization as a result of aromaticity, does not give conventional elimination, as it would lead to a very unstable benzyne intermediate.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
ウィキペディアで「Dehydrohalogenation」の詳細全文を読む



スポンサード リンク
翻訳と辞書 : 翻訳のためのインターネットリソース

Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.