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Dibenzofuran : ウィキペディア英語版
Dibenzofuran

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Dibenzofuran is a heterocyclic organic compound with the chemical structure shown at right. It is an aromatic compound that has two benzene rings fused to a central furan ring. All the numbered carbon atoms have a hydrogen atom bonded to each of them (not shown in the image). It is a volatile white solid that is soluble in nonpolar organic solvents. It is obtained from coal tar, where it exists as a 1% component.〔Gerd Collin and Hartmut Höke "Benzofurans" in Ullmann's Encyclopedia of Industrial Chemistry, 2007, Wiley-VCH, Weinheim. 〕
==Reactions==
Dibenzofuran is extremely stable, and this property is exploited by the use of DBF as a heat transfer agent.
It undergoes electrophilic reactions, such as halogenation and Friedel-Crafts reactions. Reaction of DBF with bultyl lithium results in dilithiation.〔Ulrich Iserloh, Yoji Oderaotoshi, Shuji Kanemasa, and Dennis P. Curran "Synthesis of (R,R)-4,6-Dibenzofurandiyl-2,2'-Bis (4-Phenyloxazoline) (DBFOX/PH) – A Novel Trridentate Ligand" Org. Synth. 2003, 80, 46.〕

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