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翻訳と辞書　辞書検索 [ 開発暫定版 ] スポンサード リンク Dibenzopentalene ： ウィキペディア英語版 Dibenzopentalene Dibenzopentalene (dibenzo()pentalene or dibenzo()pentalene) is an organic compound and a hydrocarbon with formula C16H10. It is of some scientific interest as a stable derivative of the highly reactive antiaromatic pentalene by benzannulation. The first derivative was synthesised in 1912 by Brand.〔Brand, K. Über Gefärbte Kohlenwasserstoffe der Diphensuccinden-Reihe. Ber. Detsch. Chem. Ges. 1912, 45, 3071-3077〕 The parent compound was reported in 1952. The NICS value for the 5-membered rings is estimated at 7.4 ppm and that of the six-membered rings 9.8 ppm.〔 Aromatic dicationic salts can be obtained by reaction with antimony pentafluoride in sulfuryl chloride. The dianion forms by reaction with butyllithium. The aromatic nature of the dianion has been confirmed by X-ray analysis. Another isomer of this compound exists called dibenzo()pentalene with one of the benzene rings positioned on the other available pentalene face. ==References== 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Dibenzopentalene」の詳細全文を読む スポンサード リンク 翻訳と辞書 : 翻訳のためのインターネットリソース Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.