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Diborane(4) : ウィキペディア英語版
Diborane(4)

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Diborane(4) (systematically named di-μ''H''-''catena''-diborane(4) and di-μ-hydrido-bis(hydridoboron)(''B''—''B'')) is a inorganic compound with the chemical formula .
== Structure and bonding ==

Computational studies predict two structures, both of which contain a boron–boron bond. In the ground state, there are two hydrogens bridging the two boron atoms via three-centre two-electron bonds in addition to one additional hydrogen on each boron. The electrons of boron–boron bond are unusually localized to a region between these two atoms, creating a notable negative charge on the side of the B–B axis away from the hydrogen bridges. This non-nuclear attractor may be involved in interactions with other molecules as an electron-donor.〔
In the excited state, the hydrogens are each attached by more traditional (two-centre two-electron) covalent bonding, two on each boron. Only the boron–boron bond links the two boron atoms, and the hydrogens on one boron are twisted compared to those on the other.〔

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