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|Section2= |Section3= }} Diindenoperylene (DIP) is an organic semiconductor which receives attention because of its potential application in optoelectronics (solar cells, OLEDs) and electronics (RFID tags). DIP is a planar perylene derivative with two indeno-groups attached to opposite sides of the perylene core. Its chemical formula is C32H16, the full chemical name is diindeno()perylene. Its chemical synthesis has been described.〔J. von Braun, G. Manz, in Deutsches Reichspatentamt, Berlin. (Germany, 1934).〕〔E. Clar, Polycyclic hydrocarbons (Academic Press, London, New York, 1964), p. 2〕 The molecular weight is 400.48 g/mol, the dimensions of the molecule in its plane are ~18.4×7 Å. and its sublimation temperature is above 330 °C.〔A. C. Dürr, Ph.D. thesis, Universität Stuttgart (2002)〕 It is non-polar and therefore only slightly soluble, for example in acetone. DIP is a red dye and has been used as active material for optical recording.〔H. E. Simmons. (1987)〕 Because of its ‘perylene-type’ optical emission in the visible spectrum, it has also been used in organic light emitting diodes.〔H. Antoniadis, A. J. Bard. (Hewlett-Packard Company & The Board of Regents of The University of Palo Alto, CA, 1997)〕 Organic field effect transistors of DIP have been studied.〔M. Münch, Ph.D. thesis, Universität Stuttgart (2001)〕 The charge carrier mobility achieved was up to 0.1 cm²/(V·s) for thin film transistors with silicon dioxide as gate dielectric, making DIP a good candidate for further optimisation.〔N. Karl, in (Organic Electronic Materials ) R. Farchioni, G. Grosso, Eds. (Springer, Berlin, 2001), vol. II, ISBN 3-540-66721-0 pp. 283 ff.〕 The structure of bulk DIP crystals has recently been studied by Pflaum et al., who found two distinct phases at room temperature and at temperatures above 160 °C. In thin films for growth ‘near equilibrium’ (at substrate temperature of about 130 °C) by organic molecular beam deposition (OMBD), DIP has been shown to order very well.〔〔 The structure of thin DIP films has been characterized ‘post-growth’,〔 with structures differing from the room-temperature bulk structure. These thin-film structures depend on the substrate used, and also on the substrate temperature during growth. ==References== 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Diindenoperylene」の詳細全文を読む スポンサード リンク
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