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Dimethylmagnesium
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Dimethylmagnesium : ウィキペディア英語版
Dimethylmagnesium

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Dimethylmagnesium is an organomagnesium compound. Like other dialkylmagnesium compounds, it is prepared by adding at least one equivalent of dioxane to a solution of methylmagnesium halide:
:2 CH3MgX + dioxane (CH3)2Mg + MgX2(dioxane)
The complex of magnesium dihalide and dioxane precipitates as a solid, driving the Schlenk equilibrium to give the dialkylmagnesium compound, which remains in solution.
The structure of this compound has been determined by X-ray crystallography. The material is a polymer with tetrahedral magnesium centres, each surrounded by bridging methyl groups. The Mg-C distances are 224 pm.
==References==


抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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