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Dithiobiuret : ウィキペディア英語版
Dithiobiuret

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Dithiobiuret is an organosulfur compound with the formula HN(C(S)NH2)2. It is a colourless solid that is soluble in warm water and polar organic solvents. It is a planar molecule with short C-S and C-N distances (1.69, 1.38 Å, resp.) indicative of multiple C-S and C-N bonding.〔Spofford, W. A., III; Amma, E. L. "Crystal and molecular structure of dithiobiuret" Journal of Crystal and Molecular Structure 1972, vol. 2, 151-8. 〕
The compound can be viewed as the product from the condensation of two molecules of thiourea, but it is prepared by treatment of 2-cyanoguanidine with hydrogen sulfide. The conversion proceeds via guanylthiourea:
:NCNC(NH2) + H2S → HN(C(S)NH2)(C(NH)NH2)
:HN(C(S)NH2)(C(NH)NH2) + H2S → HN(C(S)NH2)2
It is used as a plasticizer, a rubber accelerator, and as an intermediate in pesticide manufacturing.〔(Dithiobiuret Hazardous Substance Fact Sheet ), New Jersey Department of Health and Senior Services〕 It is extremely toxic; exposure can result in respiratory failure.
==See also==

* Biuret


抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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