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An electrochemical gradient is a gradient of electrochemical potential, usually for an ion that can move across a membrane. The gradient consists of two parts, the electrical potential and a difference in the chemical concentration across a membrane. The difference of electrochemical potentials can be interpreted as a type of potential energy available for work in a cell. The energy is stored in the form of chemical potential, which accounts for an ion's ''concentration gradient'' across a cell membrane, and electrostatic energy, which accounts for an ion's tendency to move under influence of the transmembrane potential. ==Overview== Electrochemical potential is important in electroanalytical chemistry and industrial applications such as batteries and fuel cells. It represents one of the many interchangeable forms of potential energy through which energy may be conserved. In biological processes, the direction an ion moves by diffusion or active transport across a membrane is determined by the electrochemical gradient. In mitochondria and chloroplasts, proton gradients are used to generate a chemiosmotic potential that is also known as a proton motive force. This potential energy is used for the synthesis of ATP by oxidative phosphorylation. An electrochemical gradient has two components. First, the electrical component is caused by a charge difference across the lipid membrane. Second, a chemical component is caused by a differential concentration of ions across the membrane. The combination of these two factors determines the thermodynamically favourable direction for an ion's movement across a membrane. An electrochemical gradient is analogous to the water pressure across a hydroelectric dam. Membrane transport proteins such as the sodium-potassium pump within the membrane are equivalent to turbines that convert the water's potential energy to other forms of physical or chemical energy, and the ions that pass through the membrane are equivalent to water that ends up at the bottom of the dam. Also, energy can be used to pump water up into the lake above the dam. In similar manner, chemical energy in cells can be used to create electrochemical gradients. 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Electrochemical gradient」の詳細全文を読む スポンサード リンク
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