|
Ethers are a class of organic compounds that contain an ether group—an oxygen atom connected to two alkyl or aryl groups—of general formula R–O–R'. These ethers can again be classified into two varieties, if the alkyl groups are the same on both sides of the oxygen atom then it is a simple or symmetrical ether. Whereas if they are different the ethers are called mixed or unsymmetrical ethers A typical example is the solvent and anesthetic diethyl ether, commonly referred to simply as "ether" (CH3-CH2-O-CH2-CH3). Ethers are common in organic chemistry and pervasive in biochemistry, as they are common linkages in carbohydrates and lignin. ==Structure and bonding== Ethers feature C-O-C linkage defined by a bond angle of about 110° and C-O distances of about 140 pm. The barrier to rotation about the C-O bonds is low. The bonding of oxygen in ethers, alcohols, and water is similar. In the language of valence bond theory, the hybridization at oxygen is sp3. Oxygen is more electronegative than carbon, thus the hydrogens alpha to ethers are more acidic than in simple hydrocarbons. They are far less acidic than hydrogens alpha to carbonyl groups (such as in ketones or aldehydes), however. :Depending on the groups at R and R', ethers are classified into two types: # Simple ethers or symmetrical ethers; e.g., Diethyl ether, dimethyl ether, etc. # Mixed ethers or asymmetrical ethers; e.g., Methyl ethyl ether, Methyl phenyl ether, etc. 抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Ether」の詳細全文を読む スポンサード リンク
|