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Evapoporometry : ウィキペディア英語版 | Evapoporometry Evapoporometry is a method used to determine pore-size in synthetic membranes. Based on the kelvin equation, this technique is most accurate for determination of pore diameters between 4 nm to 150 nm.〔 〕 ==Theory== Evapoporometry uses modified forms of the kelvin equation to relate the evaporation of a volatile liquid (usually 2-propanol) from a membrane to the average diameter of the pores in that membrane.〔 The first modified equation used in this technique is:
Where is the instantaneous vapor pressure of the volatile liquid, is the normal vapor pressure, is the surface tension, is the liquid molar volume, is the gas constant, is the absolute temperature, and is the pore diameter.〔 Since these pressures can be expressed as mole fractions, the equation is further modified to relate these mole fractions to evaporation rate in the following equation: Where and are mole fractions, is the evaporation rate during pore draining, is the evaporation rate of the initial liquid film over the membrane, is the diameter of the testing cell, and is a constant.〔
抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Evapoporometry」の詳細全文を読む
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