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Evapoporometry : ウィキペディア英語版
Evapoporometry
Evapoporometry is a method used to determine pore-size in synthetic membranes. Based on the kelvin equation, this technique is most accurate for determination of pore diameters between 4 nm to 150 nm.〔 〕
==Theory==
Evapoporometry uses modified forms of the kelvin equation to relate the evaporation of a volatile liquid (usually 2-propanol) from a membrane to the average diameter of the pores in that membrane.〔 The first modified equation used in this technique is:
ln = -
Where p'A is the instantaneous vapor pressure of the volatile liquid, p^A is the normal vapor pressure, y is the surface tension, V_\text is the liquid molar volume, R is the gas constant, T is the absolute temperature, and d is the pore diameter.〔 Since these pressures can be expressed as mole fractions, the equation is further modified to relate these mole fractions to evaporation rate in the following equation:

Where X_\text and X^_\text are mole fractions, W_\text is the evaporation rate during pore draining, W^_\text is the evaporation rate of the initial liquid film over the membrane, d_\text is the diameter of the testing cell, and k_\text is a constant.〔

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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