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Furoin : ウィキペディア英語版
Furoin

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Furoin or 1,2-di(furan-2-yl)-2-hydroxyethanone is an organic compound with formula C10H8O4. It can be produced from furfural by the catalytic action of cyanide ions.〔
Denis Lorient (1999), ''(New ingredients in food processing: biochemistry and agriculture ).'' Woodhead Publishing.
ISBN 1-85573-443-5. 366 pages

==Reactions==
Furoin synthesis from furfural is also catalyzed by vitamin B1 (thiamine). In 1957, R. Breslow proposed that this reaction involves a relatively stable carbene form of thiamine:〔

〕〔

〕 In the catalytic cycle shown below two molecules of furfural react to give furoin, via a thiazol-2-ylidene catalyst, resulting from loss of one proton at carbon 2 of the thiazolium cation of vitamin B1:
This was the first evidence for the existence of persistent carbenes.

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