翻訳と辞書 |
Furoin
|Section2= |Section3= }} Furoin or 1,2-di(furan-2-yl)-2-hydroxyethanone is an organic compound with formula C10H8O4. It can be produced from furfural by the catalytic action of cyanide ions.〔 Denis Lorient (1999), ''(New ingredients in food processing: biochemistry and agriculture ).'' Woodhead Publishing. ISBN 1-85573-443-5. 366 pages 〕 ==Reactions== Furoin synthesis from furfural is also catalyzed by vitamin B1 (thiamine). In 1957, R. Breslow proposed that this reaction involves a relatively stable carbene form of thiamine:〔 〕〔 〕 In the catalytic cycle shown below two molecules of furfural react to give furoin, via a thiazol-2-ylidene catalyst, resulting from loss of one proton at carbon 2 of the thiazolium cation of vitamin B1: This was the first evidence for the existence of persistent carbenes.
抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)』 ■ウィキペディアで「Furoin」の詳細全文を読む
スポンサード リンク
翻訳と辞書 : 翻訳のためのインターネットリソース |
Copyright(C) kotoba.ne.jp 1997-2016. All Rights Reserved.
|
|