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HCFCs : ウィキペディア英語版
Chlorofluorocarbon
A chlorofluorocarbon (CFC) is an organic compound that contains only carbon, chlorine, and fluorine, produced as a volatile derivative of methane, ethane, and propane. They are also commonly known by the DuPont brand name Freon. The most common representative is dichlorodifluoromethane (R-12 or Freon-12). Many CFCs have been widely used as refrigerants, propellants (in aerosol applications), and solvents. Because CFCs contribute to ozone depletion in the upper atmosphere, the manufacture of such compounds has been phased out under the Montreal Protocol, and they are being replaced with other products such as hydrofluorocarbons (HFCs)〔("Climate Change." ) The White House. 6 August 2014.〕 (e.g., R-410A), hydrocarbons, and CO2. However, these replacements are sometimes considered pollutants in their own right.〔(Ozone layer treaty could tackle super polluting HFCs ). rtcc.org. 15 July 2014〕
== Structure, properties and production ==
(詳細はalkanes, carbon in the CFCs and the HCFCs is tetrahedral. Because the fluorine and chlorine atoms differ greatly in size and effective charge from hydrogen and from each other, the methane-derived CFCs deviate from perfect tetrahedral symmetry.〔Siegemund, Günter ''et al.'' (2002) "Fluorine Compounds, Organic" in ''Ullmann's Encyclopedia of Industrial Chemistry'', Wiley-VCH, Weinheim. 〕
The physical properties of CFCs and HCFCs are tunable by changes in the number and identity of the halogen atoms. In general they are volatile, but less so than their parent alkanes. The decreased volatility is attributed to the molecular polarity induced by the halides, which induces intermolecular interactions. Thus, methane boils at −161 °C whereas the fluoromethanes boil between −51.7 (CF2H2) and −128 °C (CF4). The CFCs have still higher boiling points because the chloride is even more polarizable than fluoride. Because of their polarity, the CFCs are useful solvents, and their boiling points make them suitable as refrigerants. The CFCs are far less flammable than methane, in part because they contain fewer C-H bonds and in part because, in the case of the chlorides and bromides, the released halides quench the free radicals that sustain flames.
The densities of CFCs are higher than their corresponding alkanes. In general the density of these compounds correlates with the number of chlorides.
CFCs and HCFCs are usually produced by halogen exchange starting from chlorinated methanes and ethanes. Illustrative is the synthesis of chlorodifluoromethane from chloroform:
:HCCl3 + 2 HF → HCF2Cl + 2 HCl
The brominated derivatives are generated by free-radical reactions of the chlorofluorocarbons, replacing C-H bonds with C-Br bonds. The production of the anesthetic 2-bromo-2-chloro-1,1,1-trifluoroethane ("halothane") is illustrative:
:CF3CH2Cl + Br2 → CF3CHBrCl + HBr

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
ウィキペディアで「Chlorofluorocarbon」の詳細全文を読む



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