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Hydrogen bond : ウィキペディア英語版
Hydrogen bond

A hydrogen bond is the electrostatic attraction between polar groups that occurs when a hydrogen (H) atom bound to a highly electronegative atom such as nitrogen (N), oxygen (O) or fluorine (F) experiences attraction to some other nearby highly electronegative atom.
These hydrogen-bond attractions can occur between molecules (''intermolecular'') or within different parts of a single molecule (''intramolecular''). The hydrogen bond (5 to 30 kJ/mole) is stronger than a van der Waals interaction, but weaker than covalent or ionic bonds. This type of bond can occur in inorganic molecules such as water and in organic molecules like DNA and proteins.
Intermolecular hydrogen bonding is responsible for the high boiling point of water (100 °C) compared to the other group 16 hydrides that have no hydrogen bonds. Intramolecular hydrogen bonding is partly responsible for the secondary and tertiary structures of proteins and nucleic acids. It also plays an important role in the structure of polymers, both synthetic and natural.
In 2011, an IUPAC Task Group recommended a modern evidence-based definition of hydrogen bonding, which was published in the IUPAC journal ''Pure and Applied Chemistry''. This definition specifies that ''The hydrogen bond is an attractive interaction between a hydrogen atom from a molecule or a molecular fragment X–H in which X is more electronegative than H, and an atom or a group of atoms in the same or a different molecule, in which there is evidence of bond formation.'' An accompanying detailed technical report provides the rationale behind the new definition.
==Bonding==

A hydrogen atom attached to a relatively electronegative atom will play the role of the hydrogen bond ''donor''. This electronegative atom is usually fluorine, oxygen, or nitrogen. A hydrogen attached to carbon can also participate in hydrogen bonding when the carbon atom is bound to electronegative atoms, as is the case in chloroform, CHCl3. An example of a hydrogen bond donor is the hydrogen from the hydroxyl group of ethanol, which is bonded to an oxygen.
An electronegative atom such as fluorine, oxygen, or nitrogen will be the hydrogen bond ''acceptor'', whether or not it is bonded to a hydrogen atom. An example of a hydrogen bond acceptor that does not have a hydrogen atom bonded to it is the oxygen atom in diethyl ether.
In the donor molecule, the electronegative atom attracts the electron cloud from around the hydrogen nucleus of the donor, and, by decentralizing the cloud, leaves the atom with a positive partial charge. Because of the small size of hydrogen relative to other atoms and molecules, the resulting charge, though only partial, represents a large charge density. A hydrogen bond results when this strong positive charge density attracts a lone pair of electrons on another heteroatom, which then becomes the hydrogen-bond acceptor.
The hydrogen bond is often described as an electrostatic dipole-dipole interaction. However, it also has some features of covalent bonding: it is directional and strong, produces interatomic distances shorter than the sum of the van der Waals radii, and usually involves a limited number of interaction partners, which can be interpreted as a type of valence. These covalent features are more substantial when acceptors bind hydrogens from more electronegative donors.
The partially covalent nature of a hydrogen bond raises the following questions: "To which molecule or atom does the hydrogen nucleus belong?" and "Which should be labeled 'donor' and which 'acceptor'?" Usually, this is simple to determine on the basis of interatomic distances in the X−HY system, where the dots represent the hydrogen bond: the X−H distance is typically ≈110 pm, whereas the HY distance is ≈160 to 200 pm. Liquids that display hydrogen bonding (such as water) are called associated liquids.
Hydrogen bonds can vary in strength from very weak (1–2 kJ mol−1) to extremely strong (161.5 kJ mol−1 in the ion ). Typical enthalpies in vapor include:
* F−H:F (161.5 kJ/mol or 38.6 kcal/mol)
* O−H:N (29 kJ/mol or 6.9 kcal/mol)
* O−H:O (21 kJ/mol or 5.0 kcal/mol)
* N−H:N (13 kJ/mol or 3.1 kcal/mol)
* N−H:O (8 kJ/mol or 1.9 kcal/mol)
* HO−H: (18 kJ/mol or 4.3 kcal/mol; data obtained using molecular dynamics as detailed in the reference and should be compared to 7.9 kJ/mol for bulk water, obtained using the same molecular dynamics.)
Quantum chemical calculations of the relevant interresidue potential constants (compliance constants) revealed large differences between individual H bonds of the same type. For example, the central interresidue N−H···N hydrogen bond between guanine and cytosine is much stronger in comparison to the N−H···N bond between the adenine-thymine pair.
The length of hydrogen bonds depends on bond strength, temperature, and pressure. The bond strength itself is dependent on temperature, pressure, bond angle, and environment (usually characterized by local dielectric constant). The typical length of a hydrogen bond in water is 197 pm. The ideal bond angle depends on the nature of the hydrogen bond donor. The following hydrogen bond angles between a hydrofluoric acid donor and various acceptors have been determined experimentally:

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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