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Imidogen : ウィキペディア英語版
Imidogen

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Imidogen (systematically named λ1-azane and hydridonitrogen), also called aminylene or nitrene, is and inorganic compound with the chemical formula NH (also written ()). Imidogen can be synthesized from an ammonia discharge;〔Campbell, W.C.; Tsikata, E.; van Buuren, L.; Lu, H.; Doyle, J.M.; ''Phys. Rev. Lett.'' 2007, ''98'', 213001.〕 the resulting radicals are highly reactive and consequently short lived, but form an important part of radical chemistry. Imidogen is interesting in that it reacts differently depending on its spin multiplicity. Also, it has a triplet ground state. In sufficiently high concentrations, imidogen polymerizes to form triazidine that, without stabilizing substituents, is in itself only a metastable molecule.
== Nomenclature ==

The trivial name ''nitrene'' is the preferred IUPAC name. The systematic names, ''λ1-azane'' and ''hydridonitrogen'', valid IUPAC names, are constructed according to the substitutive and additive nomenclatures, respectively.
In appropriate contexts, imidogen can be viewed as ammonia with two hydrogen atoms removed, and as such, ''azylidene'' may be used as a context-specific systematic name, according to substitutive nomenclature. By default, this name pays no regard to the radicality of the imidogen molecule. Although, in even more specific context, it can also name the non-radical state, whereas the diradical state is named ''azanediyl''.
''Imidogen'' is constructed from the word 'imide' and the suffix '-gen', intended to mean 'generator of imide', referring to imidogen's propensity to from imides in reactions.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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