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Lactol : ウィキペディア英語版
Lactol

In organic chemistry, a lactol is the cyclic equivalent of a hemiacetal or a hemiketal.
The compound is formed by the intramolecular nucleophilic addition of a hydroxyl group to the carbonyl group of an aldehyde or a ketone.
〔IUPAC Gold Book (lactols )〕
A lactol is often found as an equilibrium mixture with the corresponding hydroxyaldehyde. The equilibrium can favor either direction depending on ring size and other conformational effects.
:
The lactol functional group is prevalent in nature as component of aldose sugars.
==Chemical reactivity==

Lactols can participate in a variety of chemical reactions including:
* Oxidation to form lactones
* Reaction with alcohols to form acetals
*
* The reaction of sugars with alcohols or other nucleophiles leads to the formation of glycosides
* Reduction (deoxygenation) to form cyclic ethers

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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