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Lignosulfonates, or sulfonated lignin, (CAS number 8062-15-5) are water-soluble anionic polyelectrolyte polymers: they are byproducts from the production of wood pulp using sulfite pulping. Most delignification in sulfite pulping involves acidic cleavage of ether bonds, which connect many of the constituents of lignin. The electrophilic carbocations produced during ether cleavage react with bisulfite ions (HSO3−) to give sulfonates. :R-O-R' + H+ → R+ + R'OH :R+ + HSO3− → R-SO3H The primary site for ether cleavage is the α-carbon (carbon atom attached to the aromatic ring) of the propyl (linear three carbon) side chain. The following structures do not specify the structure since lignin and its derivatives are complex mixtures: the purpose is to give a general idea of the structure of lignosulfonates. The groups R1 and R2 can be a wide variety of groups found in the structure of lignin. Sulfonation occurs on the side chains, not on the aromatic rings, like in p-toluenesulfonic acid. Lignosulfonate have very broad ranges of molecular mass (they are very polydisperse). A range of from 1000–140,000 da has been reported for softwood lignosulfonates with lower values reported for hardwoods.〔 ==Preparation== Lignosulfonates are recovered from the spent pulping liquids (red or brown liquor) from sulfite pulping. The most widely used industrial process is the Howard process, in which 90–95% yields of calcium lignosulfonates (CAS number 904-76-3), are precipitated by addition of excess calcium hydroxide. Ultrafiltration and ion-exchange can also be used to separate lignosulfonates from the spent pulping liquid.〔 A list of CAS numbers for the various metal salts of lignosulfonate is available.〔(【引用サイトリンク】title=List of lignosulfonate CAS numbers )〕 抄文引用元・出典: フリー百科事典『 ウィキペディア（Wikipedia）』 ■ウィキペディアで「Lignosulfonates」の詳細全文を読む スポンサード リンク
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