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MXenes
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MXenes : ウィキペディア英語版
MXenes
In materials science, MXenes are a class of two-dimensional inorganic compounds (i.e. graphene, which is the most famous member of two-dimensional materials family). These materials consist of few atoms thick layers of transition metal carbide or carbonitrides. First described in 2011, MXenes combine metallic conductivity of transition metal carbides and hydrophilic nature because of their hydroxyl or oxygen terminated surfaces.
==Structure==

As-synthesized MXenes prepared via HF etching have an accordion-like morphology, which can be referred to as a multi-layer MXene (ML-MXene), or a few-layer MXene (FL-MXene) when there are fewer than five layers. Because the surfaces of MXenes can be terminated by functional groups, the naming convention Mn+1XnTx can be used, where T is a functional group (e.g. O, F, OH).〔
MXenes adopt three structures, as inherited from the parent MAX phases: M2C, M3C2, and M4C3. They are produced by selectively etching out the A element from a MAX phase, which has the general formula Mn+1AXn, where M is an early transition metal, A is an element from group IIIA or IVA of the periodic table, X is C and/or N, and n = 1, 2, or 3. MAX phases have a layered hexagonal structure with P63/mmc symmetry, where M layers are nearly closed packed and X atoms fill octahedral sites.〔 Therefore, Mn+1Xn layers are interleaved with the A element, which is metallically bonded to the M element.

抄文引用元・出典: フリー百科事典『 ウィキペディア(Wikipedia)
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